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METHOD FOR MANUFACTURING CONJUGATED DIENE POLYMER WITH MODIFIED END, CONJUGATED DIENE POLYMER WITH

2025-06-18 01:594990下载
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FIELD : chemistry. SUBSTANCE : invention relates to a method of producing a conjugated diene polymer with a modified end. Method of producing a conjugated diene polymer with a modified end includes polymerising a conjugated diene compound using a polymerisation catalyst composition and modifying the polymer obtained by polymerisation using a modifier. Catalyst composition contains a rare earth compound and a coordination compound having a cyclopentadiene skeleton selected from substituted or unsubstituted cyclopentadienes, substituted or unsubstituted indenes, and substituted or unsubstituted fluorenes, and the polymerisation and modification is carried out in one step. EFFECT : invention simplifies the method of producing conjugated diene polymer with an extremely high proportion of cis-bonds, improves brittle fracture resistance, wear resistance and crack propagation resistance of a rubber composition. 10 cl, 2 tbl


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