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The present invention relates to a Re-Fe-Co-Sb-based thermoelectric composite and a manufacturing method thereof. The Re-Fe-Co-Sb-based thermoelectric composite is formed of a Re-Fe-Co-Sb-based matrix and a transition metal alloy, wherein the transition metal alloy is formed in the Re-Fe-Co-Sb-based thermoelectric matrix, thereby improving a thermoelectric performance index.COPYRIGHT KIPO 2018