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The present disclosure relates to an oxidation-resistant heat-resistant alloy and a preparing method. The oxidation-resistant heat-resistant alloy of the present disclosure, by mass percentage, includes : 2.5%-6% of Al, 24%-30% of Cr, 0.3%-0.55% of C, 30%-50% of Ni, 2%-8% of W, 0.01%-0.2% of Ti, 0.01%-0.2% of Zr, 0.01%-0.4% of Hf, 0.01%-0.2% of Y, 0.01%-0.2% of V, N<0.05%, 0<0.003%, S<0.003%, and Si<0.5%, the balance being Fe and inevitable impurities; wherein merely one of Ti and V is comprised. The method for preparing the oxidation-resistant heat-resistant alloy includes : smelting with inactive element materials→refining→adding mixed rare earth→adding slag→alloying active elements.