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A family of crystalline aluminosilicate zeolites has been synthesized that is a layered pentasil zeolite. These zeolites are represented by the empirical formula : Mmn+Rrp+ Al1-xExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as sodium or strontium, R can be a mixture of organoammonium cations and E is a framework element such as gallium, iron, boron, or indium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.