The thermal barrier coating system

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A thermal barrier coating (TBC) system (450) capable of self-healing has a substrate (420), a metal-based advanced bond coat (435) overlying the substrate and a ceramic top coat (440) overlying the bond coat. The bond coat (435) comprises ceramic oxide precursor materials capable of forming a non-alumina ceramic oxide composition when exposed to a thermally conditioning oxidizing environment. Embodiments of such bond coat (435) comprise rare earth elements in a range of 1-20 weight percent, and Hf in a range of about 5 to 30 weight percent or Zr in a range of about 2 to 20 weight percent. Examples of self-healing TBC systems (400, 402, 404) are provided using such bond coat (435) or its advanced bond coat chemistries in combination with conventional bond coats (433, 437) or conventional bond coat chemistries.