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The present invention provides an apparatus for selectively separating polyurethane foam and fiber from Automobile Shredder Residue (ASR). The apparatus includes a first separator, a second separator, and a third separator. The first separator primarily separates fine particles, such as dirt or glass pieces, from the ASR at a front portion thereof and separates large-sized polyurethane foam and fiber from the ASR at a rear portion thereof. The second separator grinds remaining materials after the primary separation of the first separator. The third separator separates medium-sized polyurethane foam and fiber from the remaining materials after the separation of the first separator and secondarily separates plastics, rubber, and other materials.