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To obtain an optical component having excellent secondary optical nonlinear properties by irradiating a surface and/or inside of glass having at least one member selected from Ni, Fe, V, Cu, Cr and Mn as a heat source material for absorbing and converting a laser beam to heat, incorporated to a glass matrix comprising at least one glass-forming oxide selected from SiO 2 , GeO 2 , B 2 O 3 , P 2 O 5 , TeO 2 , Ga 2 O 3 , V 2 O 5 , MoO 3 and WO 3 and at least one member selected from alkali metals, alkaline earth metals, rare earth elements and transition elements, with a laser beam with a wavelength to be absorbed by the heat source material, to convert the irradiated portion to a single crystal or a group of crystal grains comprising components contained in the glass matrix and not containing the heat source material, thereby to form a pattern.