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A SiAlON armor ceramic made from a starting powder mixture including silicon nitride powder. The armor ceramic includes a ceramic body that has between about 64 weight percent and about 90 weight percent alpha SiAlON phase that contains an alpha SiAlON-bound rare earth element. The ceramic body also has between about 5 weight percent and about 35 weight percent of a beta SiAlON phase of the formula Si6−zAlzOzN8−z wherein the value of “z” ranges between about 0.10 and about 0.35. The alpha SiAlON-bound rare earth element in the alpha SiAlON phase is present as a result of the starting powder mixture that contains between about 1 weight percent and about 7 weight percent of an oxide of the alpha SiAlON-bound rare earth element. The ceramic body has a fracture toughness (KIC) greater than about 6.00 MPa·m1/2 and a Vickers hardness (HVN) equal to greater than about 19.3 GPa.