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PURPOSE : An anti-reflective and ultra hydrophilic film structure and a manufacturing method thereof are provided to be applied to various fields like a display, a window, a solar cell by being easily and simply manufactured.CONSTITUTION : A rare earth hydroxide nano rod is deposited and annealed on a substrate. A film structure, in which a rare earth hydroxide nano rod layer is coated on the substrate, is obtained. A silica nano particle is deposited and annealed on an obtained film structure. Rare earth hydroxide is a hydration lanthanum.COPYRIGHT KIPO 2012