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The present invention provides a method of producing a crystalline metal sulfide nanostructure. The method comprising : providing a metal precursor solution and providing a sulfur precursor solution; placing a porous membrane between the metal precursor solution and the sulfur precursor solution, wherein metal cations of the metal precursor solution and sulfur ions of the sulfur precursor solution react, thereby producing a crystalline metal sulfide nanostructure, wherein the metal is a transitional metal or a Group IV metal.