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A method for the production of styrene, the process comprising reacting toluene and syngas in one or more reactors, the reactor containing a catalyst The syngas may be produced by partial oxidation or steam reforming of methane, or through conversion of a biomass material The catalyst composition may be basic or neutral, and may contain one or more promoters selected from the group of alkali elements, alkaline earthe elements, rare earth elements, or Y, Zr and Nb The product stream may be separated into a puπfied styrene product and the toluene may be recycled to the reactor or reactors