Exhaust Gas-Purifying Catalyst

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A high NOx-purifying performance at high temperature conditions is achieved with a small amount of precious metal used. An exhaust gas-purifying catalyst includes a substrate, a lower layer formed on the substrate and including a first composite oxide, palladium and platinum, and an upper layer formed on the lower layer and including a second composite oxide and rhodium. The first composite oxide includes cerium, zirconium, and an element selected from the group consisting of rare-earth elements other than cerium and alkaline-earth elements. A mass ratio of platinum with respect to palladium falls within a range of 1/50 to 1/20. The second composite oxide includes zirconium and an element selected from the group consisting of rare-earth elements other than cerium and alkaline-earth elements and has an atomic ratio of cerium with respect to zirconium smaller than that of the first composite oxide.