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Enrichment method an extract containing oleocanthal, characterized in that it comprises the following successive steps : a) forming a bisulphite compound by mixing said extract with a bisulphite of alkali metal or alkaline-earth or quaternary ammonium and removing the derivatives that have not reacted with the bisulphite; b) deprotecting the bisulphite compound. The invention also relates to a method for extracting oleocanthal from virgin olive oil.