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A heat treatment was carried out in a pressurized condition on an amorphous metal ribbon containing Fe and Co as main components and being represented by the general formula : (Co(1−c)Fec)100−a−bXaYb. (In the formula, X represents at least one species of element selected from Si, B, C and Ge, Y represents at least one species of element selected from Zr, Nb, Ti, Hf, Ta, W, Cr, Mo, V, Ni, P, Al, Pt, Rh, Ru, Sn, Sb, Cu, Mn and rare earth elements, c, a and b satisfy 0≦c≦1.0, 10
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