分享好友 知识库首页 频道列表

The metallocene catalyst system containing rare earth

2025-06-18 05:202360下载
文件类型:PDF文档
文件大小:249K
The present invention relates to a catalytic system based at least on a rare-earth metallocene having, as ligand, a molecule consisting of two groups selected from the group consisting of cyclopentadienyl groups substituted at least at position 2 and 5, substituted fluorenyl groups, the unsubstituted fluorenyl group and indenyl groups substituted at least at position 2, and joined by a bridge. The catalytic system makes it possible to attain copolymers of ethylene and of 1, 3-butadiene comprising cyclic units containing 6 carbon atoms, with an insertion of the butadiene monomer into the copolymer in the form of the trans-1, 4 unit that represents more than 50 mol% of the vinyl (1, 2), 1, 4 and cyclic units.


请登录查看


反对 0
举报 0
收藏 0
打赏 0
评论 0