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PROBLEM TO BE SOLVED : To obtain a luminous oxide which shows excellent heat resistance and chemical stability, is useful for a luminophor of a high luminance capable of emitting light of colors from blue to yellow and shows afterglow by using a compound oxide having a specific composition. SOLUTION : An oxide to be used has a stuffed tridymite type structure having a composition of M1M22O4 or a kaliphilite type structure having a composition of M1M32O4 (wherein M1 is an alkaline earth metal element selected from Ca, Sr and Ba; M2 is a metal element selected from Al and Ga; and M3 is Si, Mg or Zn). Further, the alkaline earth metal element M1 of the oxide is substituted by a divalent ion of europium or a trivalent ion of other rare earth metal element provided that the substitution ratio is not more than 30 mol.% of the sum of the alkaline earth metal element ions.