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The invention aims at enabling, in a catalytic decarbonation apparatus, inert particles coated with calcium carbonate to be constantly and systematically extracted from the reactor, with no risk of clogging the discharge pipes. Therefor, said pipes (7′a, 7′b) have an inside diameter ranging between 40 and 60 mm and they have a downward incline up to their connection to an outside discharge conduit (8′), except, possibly, a horizontal portion starting from the orifice through which they emerge into the reactor (1′).