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Cellular core-containing ion photoactive the present invention refers to nano sol and process for manufacturing method is provided, more particularly photoactive ion inorganic oxide coordinates to the core is formed, the surface of core said hydrolyzed alkyl thread column harmony scandal organic based reagent cells is comprised of cellular-a core that of manufacturing an alkylated diphenylamine composition to naphtahlene nano-structure, said photoactive of ions homogeneous dispersion and inorganic oxide coordinates to the photoactive ion between, thus thereof lumping which is higher efficiency light emitting organic material to by organic outer shell even and superior dispersibility, once coating micro 5 m or more crack free coating film formation capable core- the elder brother whom it will count nano sol and process for manufacturing method relates to.