| 简介 |
The present invention provides a method for synthesizing a polybutadiene more efficiently and stably which is possible to obtain a rubber composition and a tire excellent in durability (fracture resistance, wear resistance and crack growth resistance). A method for producing a polybutadiene, where a butadiene monomer is polymerized with the existence of rare-earth element compounds represented by the following formula (i) : [in-line-formulae]M-(NQ)1(NQ)2(NQ)3 (i)[/in-line-formulae] (in the formula, M is at least one selected from lanthanides, scandium and yttrium; (NQ)1, (NQ)2 and (NQ)3 are amide groups which may be the same or different to each other, and have M-N bonds). |
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