| 简介 |
A transparent, polycrystalline ceramic is described. The ceramic comprises crystallites of the formula AxCuByDvEzFw, whereby A and C are selected from the group consisting of Li+, Na+, Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Al3+, Ga3+, In3+, C4+, Si4+, Ge4+, Sn2+/4+, Sc3+, Ti4+, Zn2+, Zr4+, Mo6+, Ru4+, Pd2+, Ag2+, Cd2+, Hf4+, W4+/6+, Re4+, Os4+, Ir4+, Pt2+/4+, Hg2+ and mixtures thereof, B and D are selected from the group consisting of Li+, Na+, K+, Mg2+, Al3+, Ga3+, In3+, Si4+, Ge4+, Sn4+, Sc3+, Ti4+, Zn2+, Y3+, Zr4+, Nb3+, Ru3+, Rh3+, La3+, Lu3+, Gd3+ and mixtures thereof, E and F are selected mainly from the group consisting of the divalent anions of S, Se and O and mixtures thereof, x, u, y, v, z and w satisfy the following formulae
[in-line-formulae]0.125<(x+u)/(y+v)≦0.55[/in-line-formulae]
[in-line-formulae]z+w=4[/in-line-formulae]
and at least 95% by weight of the crystallites display symmetric, cubic crystal structures of the spinel type, with the proviso that when A=C=Mg2+ and B=D=Al3+, E and F cannot both be O, and whereby the optoceramic is additionally doped with 100 ppm to 20 at. % of at least one optically active cation selected from the group consisting of Ce3+, Sm2+/3+, Eu2+/3+, Nd3+, Er3+, Yb3+, Co2+, Cr2+/3+/6+, V3+/4+, Mn2+, Fe2+/3+, Ni2+ and Cu2+. |
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