| 简介 |
The present invention relates to a catalytic system based at least on a rare-earth metallocene having, as ligand, a molecule consisting of two groups selected from the group consisting of cyclopentadienyl groups substituted at least at position 2 and 5, substituted fluorenyl groups, the unsubstituted fluorenyl group and indenyl groups substituted at least at position 2, and joined by a bridge. The catalytic system makes it possible to attain copolymers of ethylene and of 1, 3-butadiene comprising cyclic units containing 6 carbon atoms, with an insertion of the butadiene monomer into the copolymer in the form of the trans-1, 4 unit that represents more than 50 mol% of the vinyl (1, 2), 1, 4 and cyclic units. |
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