| 简介 |
The present invention provides a complex oxide having a composition represented by the formula Ln1-xMxNiOy; wherein Ln is a lanthanide, M is at least one element selected from the group consisting of Na, K, Li, Zn, Pb, Ba, Ca, Al, Bi, and rare earth elements being not the same as Ln; and 0≦x≦0.8; and 2.7≦y≦3.3, or the formula (Ln1-xMx)2NiOy; wherein Ln is a lanthanide, M is at least one element selected from the group consisting of Na, K, Li, Zn, Pb, Ba, Ca, Al, Bi, and rare earth elements being not the same as Ln; 0≦x≦0.8; and 3.6≦y≦4.4, the complex oxide having a negative Seebeck coefficient at 100° C. or higher. The complex oxide of the invention has a negative Seebeck coefficient and low electrical resistivity and also has excellent heat resistance, chemical durability, etc., and thus can be effectively utilized as an n-type thermoelectric material in air at high temperatures. |
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