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A method for preparing a doped optical fibre preform includes formulating, a rare earth material or a functional metal material and a co-doping agent into a doping solution, mixing a high-purity quartz powder with the doping solution, drying same at a temperature of 100°C.-150°C. for 12-48 hours, crushing and screening the same to obtain a doped quartz powder; depositing the doped quartz powder onto the surface of a target rod to form a doped core layer; replacing the doped quartz powder with the high-purity quartz powder, and depositing the high-purity quartz powder onto the surface of the doped core layer to form a quartz outer cladding; and removing the target rod, and gradually collapsing the entirety formed from the doped core layer and the quartz outer cladding at a high temperature to obtain the doped optical fibre preform.