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PROBLEM TO BE SOLVED : To provide a production method capable of converting a cyclohexasilane without generating a silane gas in reduction.SOLUTION : A production method of cyclohexasilane includes reacting a cyclic silane dianion salt represented by a formula (i) or cyclic silane diammonium salt and aluminum-based reducing agent or boron-based reducing agent. In the formula (i), X represents a halogen, a represents an integer of 0 to 6, Rto Rare each independently H, an alkyl, an aryl.