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Provided is a positive electrode active material for non-aqueous electrolyte secondary batteries which is capable of inhibiting increases in direct current resistance (DCR) during cycles. In the positive electrode active material for non-aqueous electrolyte secondary batteries, secondary particles formed by agglomerating primary particles comprising a lithium-containing transition-metal oxide each have, adhered into recesses formed in the surface thereof between neighbouring primary particles, rare-earth-compound secondary particles formed by agglomerating particles of a rare-earth compound. The rare-earth-compound secondary particles are respectively adhered to both of the neighbouring primary particles in each of the recesses. A tungsten-containing compound is adhered to interfaces between the primary particles inside the secondary particles comprising the lithium-containing transition-metal oxide.