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PROBLEM TO BE SOLVED : To provide : an electrode active substance largely improved in conductivity; an electrode material containing the electrode active substance largely improved in conductivity and method of manufacturing the same; an electrode formed using the electrode material; and a battery having a high discharge capacity at high-rate charge/discharge, and having a sufficient charge/discharge performance. SOLUTION : In the electrode active substance, a compound represented by formula : LixAyBzPO4contains sulfur or a sulfur compound, wherein : A is one or two or more selected from the group consisting of Co, Mn, Ni, Fe, Cu and Cr; B is one or two or more selected from the group consisting of Mg, Ca, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, Sc, Y and rare earth elements, and 0COPYRIGHT : (C)2010, JPO&INPIT