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For the purpose of providing a semiconductor junction element, which is configured of a semiconductor glass of an oxide not using a toxic element or a rare metal element, and various semiconductor devices using the semiconductor junction element, a semiconductor junction element of the present invention is obtained by joining semiconductor glasses that contain vanadium oxide and have different polarities. Another semiconductor junction element of the present invention is obtained by joining a semiconductor glass that contains vanadium oxide and an elemental semiconductor or compound semiconductor that has a polarity different from that of the semiconductor glass. Still another semiconductor junction element of the present invention is obtained by joining a metal and a semiconductor glass that contains vanadium oxide.