Apparatus and method for controlling oxygen permeation by non-porous oxygen anions conductive cerami

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A process for regulating the rate of permeation of oxygen through a nonporous ceramic membrane which conducts oxygen anions and contains alkaline earth metal ions. On at least one side of the nonporous ceramic membrane which conducts oxygen anions, carbon dioxide and/or a gaseous carbon dioxide precursor is added for a predetermined time, which enables an alteration of the oxygen permeability of the membrane material. This brings about reversible chemical formation of alkaline earth metal carbonates in the membrane and, as a result, alters the properties thereof for oxygen permeation. A membrane reactor equipped with a feed line for a moderator gas can be regulated in a simple manner. The membrane reactor can preferably be used for oxidation reactions and/or for removal of oxygen from gas mixtures.