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PROBLEM TO BE SOLVED : To provide an n-type thermoelectric semiconductor which is made of a rare earth boron carbide, and has a high density.
SOLUTION : The n-type thermoelectric semiconductor which is made of the rare earth boron carbide is characterized in that a metallic boride or YB25C is added to the rare earth boron carbide and the density thereof is ≥80%, and the composition thereof is a rhombohedral system or trigonal system having a composition represented by formula 1. The n-type thermoelectric semiconductor has a composition that is a rhombohedral system or trigonal system having a composition represented by formula 2.
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