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Materials, both glass and glass-ceramic, that exhibit UV-induced changes in light transmission and electrical conductivity behavior. The materials consist essentially, in mole %, of 20-40% SiO2, 10-20% AlO1.5, 35-55% SiO2+AlO1.5, at least 30% CdF2, 0-20% PbF2, and/or ZnF2, 0-15% rare earth metal fluoride, and 45-65% total metal fluorides.