Layer system

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A layer system including a substrate on which a first layer is positioned is provided. The first layer includes a thermographic material. The thermographic material is a pyrochlore phase doped with at least one rare earth material. The rare earth material is selected from the group europium, terbium, erbium, dysprosium, samarium, holmium, praseodymium, ytterbium, neodymium, and thulium. A method of a layer system is also provided.