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New compositions (I) comprise (A) one or more of hydrofluorocarbons, fluoroolefins, hydrofluoroolefins, hydrofluoroiodocarbons, fluoroiodocarbons and/or hydrocarbons, (B) one or more of rare gases, nitrogen dioxide, hydrogen sulfide and/or carbon dioxide and (C) at least one functionalized organic compound of b.pt. more than 60[deg] C under atmospheric pressure.