Tertiary alcohol having glucoskeleton adamantanediol manufacturing method

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A process for producing a tertiary alcohol having an adamantane skeleton which comprises reacting optionally substituted 2-adamantanone with a Grignard reagent in the presence of a rare earth halide. By the process in which optionally substituted 2-adamantanone is alkylated to produce a tertiary alcohol, the addition product can be efficiently produced in high yield while almost perfectly inhibiting the generation of reduction products.