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Disclosed are methods and compositions for aqueous electrodeposition of rare earth-transitiona metal alloys (e.g., samarium-cobalt alloys). Also disclosed are nanostructured magnetic coatings comprising a magnetic alloy of a rare earth metal (e.g., samarium) and a transition metal (e.g., cobalt). This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.