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Provided is a paint composition which radiates far infrared rays, emits anions and is excellent in contamination resistance, adhesive strength, corrosion resistance and durability. The paint composition comprises an inorganic pasting material; and a water-soluble top coat material. The inorganic pasting material comprises 30-40 wt% of an inorganic resin powder; 10-20 wt% of a ceramic powder selected from the group consisting of zeolite, jade, yellow soil, volcanic ash, glass bead, titanium dioxide nanoparticle, rare earth and their mixture; 5-10 wt% of anatase titanium dioxide; and the balance of silicon oxide. The water-soluble top coat material comprises 20-30 wt% of a silicone acrylic emulsion; 10-20 wt% of a ceramic powder selected from the group consisting of zeolite, jade, yellow soil, volcanic ash, glass bead, titanium dioxide nanoparticle, rare earth and their mixture; 20-30 wt% of calcium carbonate; 5-10 wt% of rutile titanium dioxide; 3-5 wt% of a silicon micropowder; and the balance of water.