With rare earth barium titanate particle surface-coated

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Disclosed is a powder consisting of composite barium titanate particles having surface deposition of a water-insoluble rare earth compound such as yttrium oxide. The powder is used advantageously as a base material for the preparation of a sintered body such as ceramic capacitors of small thickness or compact size as compared with conventional powder blends of barium titanate particles and yttrium oxide particles in respect of greatly improved uniformity in the distribution of the yttrium element. The composite barium titanate particles with surface deposition of yttrium oxide can be prepared by conducting hydrolysis of urea in an aqueous medium containing a water-soluble yttrium salt dissolved therein in the presence of barium titanate particles to deposit basic yttrium carbonate on the particle surface followed by calcination of the particles to convert the basic yttrium carbonate into yttrium oxide.