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Provided are a power generation element including a power generation material indicated by the following general formula (1), and a power generation system using the power generation element : (AxB1-x)NbO3 (1), where A and B are mutually different and represent at least one element selected from rare-earth elements, alkaline-earth metals, alkaline metals, Cd, and Bi, and x represents an atomic proportion in a numerical range of 0

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