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The present invention discloses an orange phosphor powder having a rare-earth aluminate have garnet structure, which is characterized by that its chemical composition is added with compounds of the IV and V groups elements and the stoichiometry formula of the orange phosphor powder is (ΣLn)3−xMeIVxAl5−ySiyO12−(x+y)N(x+y). Furthermore, the present invention also discloses a warm-white Light-emitting diode employing the orange phosphor powder.