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Methods which yield L-carnitine having a large particle diameter and hence having reduced hygroscopicity and by which L-carnitine can be purified to a high purity. One of the methods for purifying L-carnitine is characterized by dissolving crude L-carnitine crystals in a mixed solvent comprising a lower alkyl alcohol and water and then recrystallizing the L-carnitine. The other comprises dissolving crude L-carnitine crystals in a mixed solvent comprising a lower alkyl alcohol and water and then adding an organic solvent other than the lower alkyl alcohol to recrystallize the L-carnitine.