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PROBLEM TO BE SOLVED : To provide a solid electrolyte which is stable in various circumstances and has excellent quick response as a sensor. SOLUTION : A chloride ion conductive solid electrolyte consists of a rare earth oxychloride containing an alkali earth metal. In the preferable embodiment, the rare earth oxychloride containing the alkali earth metal is represented by a general formula Ln1-XAXOCl1-X (wherein Ln represents any of rare earth elements; A represents an alkali earth metal and X represents a value in the range of 0COPYRIGHT : (C)2003, JPO