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Quasi-crystalline alloy comprises a composition : AlwNixRuyMz (where, M = Ir, Pt, Rh, Pd, Cr, V, W, Mo, Nb, Ta, Ti, Hf, Zr, Re, Fe, Co, Y, rare earth, Si or B; and w = 68-75.0 less than x at most 25.0 y at most 25.0 less than z at most 20). - An INDEPENDENT CLAIM is also included for a layer structure comprising a substrate, especially a metallic material or super alloy, and a coating made from the above quasi-crystalline alloy.