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FIELD : technological processes, chemistry.SUBSTANCE : invention may be used in paint and varnish industry, production of plastics, ceramics, construction materials. Method for production of inorganic pigment based on complex sulfide of alkaline, alkali-earth and rare earth metals includes mixing of initial charge components and its interaction with sulfur-containing agent during heating. Sulfur-containing agent used is gaseous products of ammonium rhodanate thermolysis, and charge treatment with products of ammonium rhodanate thermolysis is carried out at the temperature of 650-700 °C with further heating up to 900-1000 °C. In the other version of invention charge is mixed with sulfur-containing agent, such as sulfur, reducing agent is located above charge, and mixture is thermally treated, then prepared product is additionally treated with sulfur-containing agent, such as gaseous products of ammonium rhodanate thermolysis, at the temperature of 650-700 °C with further heating up to 900-1000 °C.EFFECT : possibility to use less aggressive sulfidising agents, reduction of sulfidising time and simplification of process with preservation of produced pigments quality.2 cl, 1 dwg, 5 ex